کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1487778 | 1510706 | 2015 | 5 صفحه PDF | دانلود رایگان |
• The content of sulfur in activated carbon was controlled by solution process.
• The sulfur electrode with low sulfur content shows the best performance.
• The Li/S battery has capacity of 1360 mAh/g at 1 C and 702 mAh/g at 10 C.
The content of sulfur in sulfur/activated carbon composite is controlled from 32.37 wt.% to 55.33 wt.% by a one-step solution-based process. When the sulfur content is limited to 41.21 wt.%, it can be loaded into the pores of an activated carbon matrix in a highly dispersed state. On the contrary, when the sulfur content is 55.33 wt.%, crystalline sulfur can be detected on the surface of the activated carbon matrix. The best electrochemical performance can be obtained for a sulfur electrode with the lowest sulfur content. The sulfur/activated carbon composite with 32.37 wt.% sulfur afforded the highest first discharge capacity of 1360 mAh g−1 at 1 C rate and a large reversible capacity of 702 mAh g−1 at 10 C (16.75 A/g).
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Journal: Materials Research Bulletin - Volume 69, September 2015, Pages 24–28