کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1738184 1521609 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of uranium oxidation states in geological material
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی هسته ای و مهندسی
پیش نمایش صفحه اول مقاله
Study of uranium oxidation states in geological material
چکیده انگلیسی


• We have developed extraction technique for U oxidation states in solid material.
• Comparison of results with L3-edge XANES was made.
• Interferences induced by extracted redox-active Fe were identified and studied.
• Potential influence of radiation induced changes was evaluated by annealing experiments.
• Extraction results were in good agreement with XANES.

A wet chemical method to determine uranium (U) oxidation states in geological material has been developed and tested. The problem faced in oxidation state determinations with wet chemical methods is that U redox state may change when extracted from the sample material, thereby leading to erroneous results. In order to quantify and monitor U redox behavior during the acidic extraction in the procedure, an analysis of added isotopic redox tracers, 236U(VI) and 232U(IV), and of variations in natural uranium isotope ratio (234U/238U) of indigenous U(IV) and U(VI) fractions was performed. Two sample materials with varying redox activity, U bearing rock and U-rich clayey lignite sediment, were used for the tests. The Fe(II)/Fe(III) redox-pair of the mineral phases was postulated as a potentially disturbing redox agent. The impact of Fe(III) on U was studied by reducing Fe(III) with ascorbic acid, which was added to the extraction solution. We observed that ascorbic acid protected most of the U from oxidation. The measured 234U/238U ratio in U(IV) and U(VI) fractions in the sediment samples provided a unique tool to quantify U oxidation caused by Fe(III). Annealing (sample heating) to temperatures above 500 °C was supposed to heal ionizing radiation induced defects in the material that can disturb U redox state during extraction. Good agreement between two independent methods was obtained for DL-1a material: an average 38% of U(IV) determined by redox tracer corrected wet chemistry and 45% for XANES.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Radioactivity - Volume 124, October 2013, Pages 141–146
نویسندگان
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