A relationship between the natural radioactivity and mineralogical composition of the Ponnaiyar river sediments, India

The natural radiation level has been determined for the sediment samples of Ponnaiyar River, India with an aim of evaluating the radiation hazard. The average activity concentrations are within the world and Indian average values although some extreme values have been determined. The magnetic susceptibility measurement has been carried out to know the magnetization nature of the sediments. More downstream (mouth) of the river has quite higher magnetic susceptibility values. The mineralogical characterizations of the sediments have been carried out using Fourier Transform Infrared (FTIR) spectroscopic and XRD technique. The minerals such as quartz, microcline feldspar, orthoclase feldspar, kaolinite, calcite, gibbsite, montmorillonite, smectite, palygorskite and organic carbon are identified from FTIR analysis. Few minerals like zircon, monazite and hornblende are identified only in XRD analysis. The relative distribution of major minerals is determined by calculating extinction coefficient. The calculated values show that the amount of quartz is greater than microcline feldspar and very much greater than kaolinite in all the sites. The content of quartz and microcline feldspar is decreases, and kaolinite gradually increases towards the river mouth. Multivariate Statistical analyses were carried out between the parameters obtained from radioactivity analysis and other analyses to know the existing relations. Obtained results are discussed and suggested that the natural radioactivity level of the present sediments is mainly controlled by clay content and lesser extent to magnetic susceptibility.

► Natural radiation level, Mineralogical characterization and Magnetic susceptibility of river sediments have been successfully analyzed and discussed.
► Concentration of 232Th and 40K, average of the all calculated radiological parameters, content of kaolinite and magnetic susceptibility are increased towards the mouth of the river.
► Multivariate Statistical analyses were carried out between the parameters obtained from radioactivity analysis and other analyses, which shows that the natural radioactivity level of the river sediment is mainly controlled by clay content and lesser extent to magnetic susceptibility.
► In India, this is the first study to find out the relation between the natural radiation level and magnetic susceptibility in river sediments.