کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1794479 | 1023699 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of impurity doping on the partitioning of intrinsic ionic species during the growth of LiNbO3 crystal from the melt
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The segregation of intrinsic ionic species of LiNbO3 during crystallization generates electromotive force (EMF) at the growth interface. The EMF was measured during the growth of LiNbO3 crystal doped with MgO, ZnO, ZrO2 and MnO2 in the concentration range from 0 to 12Â mol% using a micro-pulling-down growth system. The influence of these impurities on the partitioning of intrinsic ionic species of LiNbO3 was examined. In the case of MgO-, ZnO- and ZrO2-doping, crystallization EMF had a minimum value at the concentration where the impurity ion changed its partitioning site from the Li-site to the Nb-site, as confirmed by Raman scattering measurements. The crystallization EMF of MnO2-doped LiNbO3 showed no such minimum value because Mn4+ ion did not change its partitioning site. These results demonstrate that it is the segregation of the intrinsic ionic species that generates the crystallization EMF rather than that of impurities and that the partitioning behavior of intrinsic ionic species of LiNbO3 is greatly affected by the partitioning site of impurity ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Crystal Growth - Volume 311, Issue 6, 1 March 2009, Pages 1553-1558
Journal: Journal of Crystal Growth - Volume 311, Issue 6, 1 March 2009, Pages 1553-1558
نویسندگان
Hiromitsu Kimura, Haruhiko Koizumi, Takashi Uchida, Satoshi Uda,