کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
187883 | 459649 | 2012 | 8 صفحه PDF | دانلود رایگان |
In this work, three-dimensional mesoporous NiO nanostructures have been synthesized by a simple ethylene glycol (EG)-mediated self-assembly route and subsequent calcination process. The synthesized nickel alkoxide precursors annealed at 300 and 500 °C exhibit different surface area, crystallinity and pore distribution, which have been characterized by scanning electron microscopy, transmission electron microscopy, selected area electron diffraction, X-ray diffraction, Fourier transform infrared spectroscopy and Nitrogen adsorption/desorption isotherms. The electrochemical properties of these NiO mesoporous nanostructures are investigated including the cycling and rate performance as anode materials for lithium-ion batteries. It is indicated that mesoporous NiO nanospheres synthesized at 500 °C exhibit better electrochemical performance than that obtained at 300 °C. The NiO nanospheres annealed at 500 °C present a reversible specific capacity of 518 mAh g−1 at a current density of 0.1 A g−1 after 60 cycles. With varying the rate from 0.1 to 8.0 A g−1, the capacity remains at 535 mAh g−1 at 2 A g−1 after 30 cycles and resumes to 582 mAh g−1 at 0.1 A g−1 after 60 cycles. The results indicate that our mesoporous NiO nanospheres are promising anode materials for lithium ion batteries.
Journal: Electrochimica Acta - Volume 80, 1 October 2012, Pages 140–147