کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
188466 | 459660 | 2012 | 7 صفحه PDF | دانلود رایگان |
An in situ sulfur deposition route has been developed for synthesizing sulfur–carbon composites as cathode materials for lithium–sulfur batteries. This facile synthesis method involves the precipitation of elemental sulfur at the interspaces between carbon nanoparticles in aqueous solution at room temperature. The product has been characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, charge–discharge measurements, and electrochemical impedance spectroscopy. The sulfur–carbon composite cathode with 75 wt.% active material thus obtained exhibits a remarkably high first discharge capacity of 1116 mAh g−1 with good cycle performance, maintaining 777 mAh g−1 after 50 cycles. The significantly improved electrochemical performance of the sulfur–carbon composite cathode is attributed to the carbon-wrapped sulfur network structure, which suppresses the loss of active material during charging/discharging and the migration of the polysulfide ions to the anode (i.e., shuttling effect). The integrity of the cathode structure during cycling is reflected in low impedance values observed after cycling. This facile in situ sulfur deposition route represents a low-cost approach to obtain high-performance sulfur–carbon composite cathodes for rechargeable Li–S batteries.
► Carbon-wrapped sulfur composite was obtained via an in situ sulfur deposition route.
► Sulfur–carbon composite suppresses the shuttle effect during charging.
► Sulfur–carbon composite shows enhanced cyclability and rate capability.
► Sulfur–carbon composite retains structural integrity and low impedance during cycling.
Journal: Electrochimica Acta - Volume 77, 30 August 2012, Pages 272–278