کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
188838 459668 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical performance of graphene/carbon electrode contained well-balanced micro- and mesopores by activation-free method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemical performance of graphene/carbon electrode contained well-balanced micro- and mesopores by activation-free method
چکیده انگلیسی

Microporous carbons (G-MCs) containing graphene was prepared by one step activation-free method of graphite oxide (GO)/poly(vinylidene fluoride) (PVDF) film. This study examined effect of mesoporous graphene as an electrical additive on the electrochemical performance of microporous carbon. Microporous carbon with a plate form was obtained with the addition of graphene compared to irregular MCs prepared without graphene. Without additional activation, G-MCs had a high specific surface area (737 m2/g) due to the combination of mesoporous graphene and microporous carbon (MCs: 686 m2/g). From the charge/discharge results, the electrochemical performance of G-MCs was higher than that of MCs prepared with PVDF alone, and the specific capacitance (311 F/g) of G-MCs was higher than MCs (249 F/g). This was suggested that well-balanced meso- and microporous features of G-MCs allow feasible ion transfer during charge/discharge, leading to maximizing the charge accumulation and the addition of graphene could provide a combination effect between excellent conducting graphene and the high microporous features of MCs.

This described superior electrochemical performance of graphene-embed microporous carbons compared to microporous alone.Figure optionsDownload as PowerPoint slideHighlights
► Microporous carbons were prepared with only carbonization of poly(vinylidene fluoride).
► 2-D mesoporous graphene was used as electrical additive for microporous carbons.
► Graphene/microporous carbon could be potential electrode materials for supercapacitor.
► Graphene/microporous carbon-based electrode showed high specific capacitance (311 F/g).
► It is probably due to the combination effect by microporous carbons and graphene.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 65, 30 March 2012, Pages 50–56
نویسندگان
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