Conducting polymer-based counter electrode for a quantum-dot-sensitized solar cell (QDSSC) with a polysulfide electrolyte

Conducting polymer materials, i.e., polythiophene (PT), polypyrrole (PPy), and poly(3,4-ethylenedioxythiophene) (PEDOT) were used to prepare counter electrodes (CEs) for quantum-dot-sensitized solar cells (QDSSCs). The QDSSC with PEDOT-CE exhibited the highest solar-to-electricity conversion efficiency (η) of 1.35%, which is remarkably higher than those of the cells with PT-CE (0.09%) and PPy-CE (0.41%) and very slightly higher than that of the cell with sputtered-gold-CE (1.33%). Electrochemical impedance spectra (EIS) show that this highest conversion efficiency of the PEDOT-based cell is due to higher electrocatalytic activity and reduced charge transfer resistance at the interface of the CE and the electrolyte, compared to those in the case of the cells with other conducting polymers and bare Au. Furthermore, the influences of morphology of the PEDOT film and the charge passed for its electropolymerization on the performance of its QDSSC were also studied. The higher porosity and surface roughness of the PEDOT matrix, with reference to those of other polymers are understood to be the reason for PEDOT to possess higher electrocatalytic activity at its interface with electrolyte.

► This is the first report on the use of conducting polymers as counter electrode catalysts for quantum-dot-sensitized solar cells (QDSSCs).
► Conducting polymer materials, i.e., polythiophene (PT), polypyrrole (PPy), and poly(3,4-ethylenedioxythiophene) (PEDOT) were used to prepare counter electrodes for QDSSCs.
► The influences of morphology of the PEDOT-based counter electrode (CE) on the performance of its QDSSC were studied.
► PEDOT electrode exhibits well electrocatalytic activity and stability in the polysulfide electrolyte.
► The efficiency for the QDSSC with PEDOT-CE (1.35%) is comparable to that of the cell with sputtered-Au CE (1.33%).