کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
190291 459695 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High lithium ion conducting Li2S–GeS2–P2S5 glass–ceramic solid electrolyte with sulfur additive for all solid-state lithium secondary batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
High lithium ion conducting Li2S–GeS2–P2S5 glass–ceramic solid electrolyte with sulfur additive for all solid-state lithium secondary batteries
چکیده انگلیسی

Glass–ceramic Li2S–GeS2–P2S5 electrolytes were prepared by a single step ball milling (SSBM) process. Various compositions of Li4−xGe1−xPxS4 from x = 0.70 to x = 1.00 were systematically investigated. Structural analysis by X-ray diffraction (XRD) showed gradual increase of the lattice constant followed by significant phase change with increasing GeS2. All-solid-state LiCoO2/Li cells were tested by constant-current constant-voltage (CCCV) charge–discharge cycling at a current density of 50 μA cm−2 between 2.5 and 4.3 V (vs. Li/Li+). In spite of the high conductivity of the solid-state electrolyte (SSE), LiCoO2/Li cells showed a large irreversible reaction especially during the first charging cycle. Limitation of instability of Li2S–GeS2–P2S5 in contact with Li was solved by using double layer electrolyte configuration: Li/(Li2S-P2S5/Li2S–GeS2–P2S5)/LiCoO2. LiCoO2 with SSEs heat-treated with elemental sulfur at elevated temperature exhibited a discharge capacity of 129 mA h g−1 at the second cycle and considerably improved cycling stability.

Figure optionsDownload as PowerPoint slideResearch highlights
► High conductivity over 1 × 10−3 S cm−1 for solid electrolyte using SSBM method.
► Solid electrolyte stability against LiCoO2 improved with elemental sulfur addition.
► Performance of all-solid-state batteries improved with double layer electrolyte.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 11, 15 April 2011, Pages 4243–4247
نویسندگان
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