کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
194367 459789 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of dopants on percolation behaviors and gas sensing characteristics of polyaniline film
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Effects of dopants on percolation behaviors and gas sensing characteristics of polyaniline film
چکیده انگلیسی

Effects of dopants on the correlation between the polyaniline (PAn) film resistance (R) and the reduction charge (Q) injected to the PAn film was investigated in dry acetonitrile solutions during electrochemical reduction by using the double potential step method. The R–Q correlation behaves as S-type curves, leading to the determination of the critical reduction charge (Qc). The latter represents the reduction charge required for the formation of a continuous partially reduced phase in the PAn film. It was observed that the PAn film doped with sodium dodecylbenzene sulphate (SDBS) yielded a smaller Qc than that doped with perchlorate, when the PAn films were electrochemically reduced under given conditions. The resistance of the pre-doped PAn film will increase significantly when the film is injected with reduction charge more than Qc. Hence, a smaller Qc means that the film can respond to very light reduction (or dedoping), being indicative of better sensing ability toward alkaline and reducing gases. This was confirmed by the increased sensitivity of the PAn/SDBS sensor toward 100 ppm NH3 vapor, compared with the PAn/ClO4− sensor.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 52, Issue 2, 25 October 2006, Pages 723–727
نویسندگان
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