Nanostructured Pt–M/C (M = Fe and Co) catalysts prepared by a microemulsion method for oxygen reduction in proton exchange membrane fuel cells

Nanostructured Pt–M/C (M = Fe and Co) catalysts have been synthesized by a microemulsion method and a high-temperature route. They have been characterized by cyclic voltammetry in 1 M H2SO4 and for oxygen reduction in proton exchange membrane fuel cells (PEMFC). The Pt–M alloy catalysts synthesized by the microemulsion method show higher electrochemical active surface area than those prepared by the high-temperature route, and some of them exhibit improved catalytic activity towards oxygen reduction compared to pure Pt. Among the various alloy catalysts investigated, the Pt–Co/C catalyst prepared by the microemulsion method shows the best performance with the maximum catalytic activity and minimum polarization loss. Mild heat treatment of the catalysts prepared by the microemulsion method at moderate temperatures (200 °C) in reducing atmosphere is found to improve the catalytic activity due to a cleaning of the surface and an increase in the electrochemical surface area.