کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
197431 459887 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enrichment of chromium-content in passive layers on stainless steel coated with polyaniline
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Enrichment of chromium-content in passive layers on stainless steel coated with polyaniline
چکیده انگلیسی

Enrichment of chromium-content in passive layers on a 304 stainless steel (SS) by coating polyaniline (PANI) has been confirmed by means of electrochemical and X-ray photoelectron spectroscope (XPS) techniques and thus prepared oxide films demonstrated to be highly stable in aggressive environment. PANI films are deposited on SS from a sulfuric acid solution with aniline monomer. The PANI-coated SS is found to maintain the passive state in a deaerated 1 M H2SO4 at 45 °C for several weeks. The passive state of SS remains in the same solution for several days even after the PANI films were completely removed. The passive layers underlying the PANI are certified to have higher chromium-content compared with the air-formed and anodically-formed oxide films on SS. It is suggested that PANI films enhance the passivation of SS by increasing the Cr2O3 content in the passive layer and by preventing the chromic oxide from directly interacting with aggressive solution.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 50, Issue 10, 15 March 2005, Pages 2001–2007
نویسندگان
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