کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
213464 462103 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermal decomposition kinetics and mechanism of magnesium bicarbonate aqueous solution
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Thermal decomposition kinetics and mechanism of magnesium bicarbonate aqueous solution
چکیده انگلیسی

Thermal decomposition kinetics and mechanism of magnesium bicarbonate in aqueous solution were investigated. Decomposition rate function, f(η) = 1 − 2/3η − (1 − η)2/3, was found to fit well with Ginstling–Brounshtein's diffusion model. The good linearity relationship of rate equation 1 − 2/3η − (1 − η)2/3 against time further validated that decomposition process of magnesium bicarbonate was partially controlled by the mode of diffusion. The apparent activation energy was calculated to be 47.05 kJ/mol, indicating that the overall decomposition process was also controlled by chemical reactions. The kinetic model was in good agreement with the experimental results. The effect of stirring speed, system temperature and the concentration of Mg2+ in Mg(HCO3)2 aqueous solution on decomposition ratio was analyzed. The decomposition ratio reached 88% at 50 °C. The formed basic magnesium carbonate was of microsphere structure. The mechanism of thermal decomposition of Mg(HCO3)2 was proposed in this paper.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Hydrometallurgy - Volume 89, Issues 3–4, December 2007, Pages 217–223
نویسندگان
, ,