کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
215986 1426248 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Densities, refractive indices, and viscosities of N,N-diethylethanol ammonium chloride–glycerol or –ethylene glycol deep eutectic solvents and their aqueous solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Densities, refractive indices, and viscosities of N,N-diethylethanol ammonium chloride–glycerol or –ethylene glycol deep eutectic solvents and their aqueous solutions
چکیده انگلیسی

In this work, we report new experimental data on density, ρ, refractive index, nD, and viscosity, η, of two deep eutectic solvents, N,N-diethylethanol ammonium chloride–glycerol (DEACG) and N,N-diethylethanol ammonium chloride–ethylene glycol (DEACEG), and their aqueous solutions, over the complete composition range, at temperatures from (298.15 to 343.15) K. Densities and viscosities were measured using the vibrating tube and the falling ball techniques, respectively, while the refractive index at the sodium D line was measured using an automatic refractometer. We aimed to represent the measured properties as a function of temperature and composition, and correlated them using the Redlich–Kister-type equation, for density, a polynomial function, for refractive index, and the Vogel–Fulcher–Tammann (VFT) equation, for viscosity.


• The densities, refractive indices, and viscosities of aqueous DES solutions were measured.
• DES are made from N,N-diethylethanol ammonium chloride + glycerol or ethylene glycol.
• The temperature studied was (298.15 to 343.15) K.
• The measured data were reported as functions of temperature and composition.
• The measured data were represented satisfactorily by the applied correlations.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 65, October 2013, Pages 65–72
نویسندگان
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