کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
215986 | 1426248 | 2013 | 8 صفحه PDF | دانلود رایگان |
In this work, we report new experimental data on density, ρ, refractive index, nD, and viscosity, η, of two deep eutectic solvents, N,N-diethylethanol ammonium chloride–glycerol (DEACG) and N,N-diethylethanol ammonium chloride–ethylene glycol (DEACEG), and their aqueous solutions, over the complete composition range, at temperatures from (298.15 to 343.15) K. Densities and viscosities were measured using the vibrating tube and the falling ball techniques, respectively, while the refractive index at the sodium D line was measured using an automatic refractometer. We aimed to represent the measured properties as a function of temperature and composition, and correlated them using the Redlich–Kister-type equation, for density, a polynomial function, for refractive index, and the Vogel–Fulcher–Tammann (VFT) equation, for viscosity.
• The densities, refractive indices, and viscosities of aqueous DES solutions were measured.
• DES are made from N,N-diethylethanol ammonium chloride + glycerol or ethylene glycol.
• The temperature studied was (298.15 to 343.15) K.
• The measured data were reported as functions of temperature and composition.
• The measured data were represented satisfactorily by the applied correlations.
Journal: The Journal of Chemical Thermodynamics - Volume 65, October 2013, Pages 65–72