کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217016 1426314 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Densities, viscosities, and excess properties of (N-methylmorpholine + cyclohexane, + benzene, and + toluene) at T = (298.15, 303.15, 313.15, 323.15) K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Densities, viscosities, and excess properties of (N-methylmorpholine + cyclohexane, + benzene, and + toluene) at T = (298.15, 303.15, 313.15, 323.15) K
چکیده انگلیسی

Densities, ρ, and viscosities, η, of binary mixtures (N-methylmorpholine + benzene, + toluene, and + cyclohexane) were measured over the whole mole fraction range at T = (298.15, 303.15, 313.15, 323.15) K. Densities and viscosities were used to compute the excess molar volumes VE, viscosity deviation Δη  , and the excess free energies of activation for viscous flow ΔG∗EΔG∗E. These data have been fitted to Redlich–Kister polynomial equation to derive the coefficients and estimate the standard deviation values. A discussion on these quantities in terms of molecular interactions is reported.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 40, Issue 4, April 2008, Pages 645–652
نویسندگان
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