کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
217377 | 1426330 | 2006 | 8 صفحه PDF | دانلود رایگان |
The mean values of the standard massic energy of combustion of caffeine in phase I (or alpha) and in phase II (or beta) measured by static-bomb combustion calorimetry in oxygen, at T = 298.15 K, are Δcu∘ (C8H10O2N4, I) = −(21823.27 ± 0.68) J · g−1 and Δcu∘ (C8H10O2N4, II) = −(21799.96 ± 1.08) J · g−1, respectively.The standard (p∘ = 0.1 MPa) molar enthalpy of formation in condensed phase for each form was derived from the corresponding standard molar enthalpies of combustion as, ΔfHm∘(C8H10O2N4,cr,I)=-(340.6±2.3)kJ·mol-1 and ΔfHm∘(C8H10O2N4,cr,II)=-(345.1±2.3)kJ·mol-1.The difference between the standard enthalpy of formation of the two polymorphs in condensed phase was also evaluated by using reaction-solution calorimetry. The obtained result, 2.04 ± 0.25 kJ · mol−1, is in agreement, within the uncertainty, with the difference between the molar enthalpies of formation obtained from combustion experiments (4.5 ± 3.2) kJ · mol−1, which can be considered as an internal test for consistency of the results.A value for the standard enthalpy of formation of caffeine in the gaseous state was proposed: ΔfHm∘(C8H10O2N4,g)=-(229.7±6.1)kJ·mol-1, estimated from the values of the standard enthalpies of formation of both crystalline forms obtained in this work, and the data on standard enthalpies of sublimation collected from the literature.
Journal: The Journal of Chemical Thermodynamics - Volume 38, Issue 12, December 2006, Pages 1515–1522