کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
220651 463345 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and characterisation of Ni-cyclam-modified spani electrodes for electrocatalysis of methanol oxidation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Preparation and characterisation of Ni-cyclam-modified spani electrodes for electrocatalysis of methanol oxidation
چکیده انگلیسی

Electrochemical redox properties of self-doped copolymer of aniline and orthanilic acid electrodeposited on glassy carbon has been studied. The best relation between both monomers has been found to be 10:1. The morphology of this polymer is a porous and open structure, due to this structure it is possible the electrochemical deposition of Ni-cyclam with a good electrocatalyst properties. The electrocatalysis of this electrode was carried out in solutions containing methanol in basic medium. The methanol electrooxidation mechanism is similar to that encountered on other catalytic electrodes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 614, Issues 1–2, 15 March 2008, Pages 8–14
نویسندگان
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