کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
26099 | 43934 | 2016 | 13 صفحه PDF | دانلود رایگان |
• Red and Near Infra-Red (NIR) emitting bis-coumarin analogues.
• The synthesized molecules are based on curcumin framework.
• Photophysical properties are studied in different microenvironments.
• Solvatochromic study based on solvent polarity functions.
Four fluorescent bis-coumarin analogues were synthesized having donor-acceptor-donor (D-A-D) system based on curcumin framework, where the 7-(diethylamino)coumarin-3-carbaldehyde has been employed as donor while the central 1,3-diketo or 1,3-diketofluoroborate is the acceptor core. The structural modifications have been made by functionalizing acetylacetone or 2-acetyl cyclopentanone to study the effect of imparting rigidity on the photophysical properties of the bis-coumarin analogues. The difluoroboron complexes of bis-coumarin analogues were synthesized to study the effect of difluoroboron complexation on the photophysical properties. The mono-coumarin analogue is synthesized to understand the nature and the contribution of the donor groups in bis-coumarin of the curcumin framework. The photophysical properties are studied in detail using solvents of differing polarity. The photophysical properties of the newly synthesized bis-coumarin molecules were compared with the priviosly reported bis-coumarin analogues.
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Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 327, 15 August 2016, Pages 58–70