Brominated flame retardants and organochlorine compounds in duplicate diet samples from a Portuguese academic community

• This is the first study of its kind reporting the levels of POPs in duplicate diet samples from Portugal.
• Low levels of BFRs, PCBs, and OCs were found in the 21 7-day duplicate diet samples.
• Estimated daily intakes below tolerable daily intakes set for PCBs and OCs and below the reference dose values for BFRs.
• Health risk associated with food consumption is low for this population.

Concentrations of persistent organic pollutants (POPs), including polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDDs), polychlorinated biphenyls (PCBs), hexachlorocyclohexane isomers (HCHs), hexachlorobenzene (HCB), chlordane compounds (CHLs) and dichlorodiphenyltrichloroethane and its metabolites (DDTs), were measured in duplicate diet samples from 21 volunteers at a Portuguese academic community (University of Aveiro). Overall, the levels of the target compounds were low, with detection frequencies varying widely depending on the compounds and with brominated flame retardants (BFRs) registering the lowest detection frequencies. Among PCB congeners, nondioxin-like PCBs were predominant and detected in the majority of the samples. Organochlorine pesticides were also detected in the majority of the samples, with 100% detection for DDTs and HCHs.Estimated daily intakes (EDIs) were calculated using lower and upper bound estimations, and in both cases values were far below the currently established tolerable daily intakes for PCBs and OCs and the reference doses for PBDEs and HBCDDs.