کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4415845 | 1307761 | 2007 | 7 صفحه PDF | دانلود رایگان |

The sonochemical degradation of the systematically substituted azo compound 2,7-dihydroxy-1-phenylazonaphthaline-3,6-disulfonic acid was investigated using a frequency of 850 kHz and an acoustic input power of 61 W. All derivatives were degraded completely within 6 h by the ultrasonic treatment. Trifluoromethyl substituted azo compounds exhibited 2–3-fold higher degradation rates in comparison to the reference hydrogen substituted azo compound (k = 0.54 h−1). In contrast to enzymatic processes (azoreductase or laccase), the ultrasonic treatment for these ortho-, meta-, and para-substituted azo compound showed 1.5–50-fold higher degradation rates. Additionally the ultrasound treatment was characterized by shorter reaction times. As a result of the detection and identification of specific intermediates using LC-MS a reaction pathway of the sonochemical degradation of the analysed azo compound is proposed indicating the formation of cyclohexadienone and naphthalene quinone derivatives.
Journal: Chemosphere - Volume 67, Issue 8, April 2007, Pages 1526–1532