Comparative study of simultaneous removal of As, Cu, and Pb using different combinations of electrokinetics with bioleaching by Acidithiobacillus ferrooxidans

Different designs of electrokinetics were applied to simultaneously remove arsenic, copper, and lead from contaminated soils. Single electrokinetics (control) resulted in superior removal efficiencies for Cu (73.5%) and Pb (88.5%), though the removal of As (3.11%) was relatively little. Sequential bioelectrokinetics of bioleaching with Acidithiobacillus ferrooxidans and electrokinetics enhanced the removal of As (25%), while Pb exhibited a significant decrease in removal efficiency (10.6%), due to the formation of insoluble compounds. In order to improve the overall performance, integrated bioelectrokinetics was designed by inoculating A. ferrooxidans into the electrolyte after 5 or 15 days of electrokinetics. Lead (75.8%) and copper (72%) were effectively removed through electrokinetics, after which arsenic (35%) was more efficiently removed by bioleaching-enhanced electrokinetics. A pilot-scale experiment indicated that integrated bioelectrokinetics is an effective means of remediation of soils contaminated with multiple heavy metals and arsenic.

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► Hybrid technique was recommended for simultaneous removal of As and heavy metals.
► Single electrokinetics, sequential and integrated bioelectrokinetics were compared.
► Integrated bioelectrokinetics was successfully achieved for simultaneous removal.
► A. ferrooxidans inoculation at 15th day of electrokinetics showed highest removal.
► Pilot-scale experiment proved that integrated bioelectrokinetics was effective.