کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4484355 1316917 2009 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A QSAR-like analysis of the adsorption of endocrine disrupting compounds, pharmaceuticals, and personal care products on modified activated carbons
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات فرآیندهای سطح زمین
پیش نمایش صفحه اول مقاله
A QSAR-like analysis of the adsorption of endocrine disrupting compounds, pharmaceuticals, and personal care products on modified activated carbons
چکیده انگلیسی

Rapid small-scale column tests (RSSCTs) examined the removal of 29 endocrine disrupting compounds (EDCs) and pharmaceutical/personal care products (PPCPs). The RSSCTs employed three lignite variants: HYDRODARCO 4000 (HD4000), steam-modified HD4000, and methane/steam-modified HD4000. RSSCTs used native Lake Mead, NV water spiked with 100–200 ppt each of 29 EDCs/PPCPs. For the steam and methane/steam variants, breakthrough occurred at 14,000–92,000 bed volumes (BV); and this was 3–4 times more bed volumes than for HD4000. Most EDC/PPCP bed life data were describable by a normalized quantitative structure–activity relationship (i.e. QSAR-like model) of the form: BVp=((TPV×ρmc)(ⅇ0.2812×pHs)CV×Co)(0.2758×χ8p+0.0011×FOSA)where TPV is the pore volume, ρmc is the apparent density, CV is the molecular volume, Co is the concentration, 8χp depicts the molecule's compactness, and FOSA is the molecule's hydrophobic surface area.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Water Research - Volume 43, Issue 15, August 2009, Pages 3849–3861
نویسندگان
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