کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4485437 1316952 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A thermodynamic analysis on adsorption of estrogens in activated sludge process
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات فرآیندهای سطح زمین
پیش نمایش صفحه اول مقاله
A thermodynamic analysis on adsorption of estrogens in activated sludge process
چکیده انگلیسی

The adsorption behaviors of estrone (E1), 17β-estradiol (E2), estriol (E3), 17α-ethinylestradiol (EE2), and equol were studied with a deactivated sludge subjected to heat treatment at 80 °C for 30 min. The heat-treatment hardly changed the adsorption features of activated sludge (AS). The adsorption equilibrium of all estrogens was approached within 10 min at 20 °C, and a high removal of estrogens was achieved simultaneously. The equilibrium data were well fitted by a Freundlich isotherm. The adsorption behaviors of E1, E2, E3 and EE2 in the AS system were independent of their Kow values. Thermodynamic analysis revealed that the adsorption behaviors of E1, E2, E3 and EE2 could be considered as an exothermic, physical and reversible process, resulting in their higher adsorption capacities at lower temperature. Regarding equol, its adsorption was an endothermic, chemical and irreversible process.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Water Research - Volume 41, Issue 11, June 2007, Pages 2341–2348
نویسندگان
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