کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4486474 1316990 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Treatment of high fluoride concentration water by MgAl-CO3 layered double hydroxides: Kinetic and equilibrium studies
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات فرآیندهای سطح زمین
پیش نمایش صفحه اول مقاله
Treatment of high fluoride concentration water by MgAl-CO3 layered double hydroxides: Kinetic and equilibrium studies
چکیده انگلیسی

MgAl-CO3 layered double hydroxides (LDHs) have been employed to treat high fluoride concentration solution. The influences of solution pH, initial fluoride concentration and other anions in the solution were investigated by a series of batch experiments. A marked decrease in the amount of adsorbed fluoride by LDHs is observed with increasing pH. The extent of fluoride removal in the presence of other anions decreases in the order HCO3−>Cl−>H2PO4−>SO42−. The equilibrium isotherm for fluoride uptake corresponds closely to the Langmuir–Freundlich (L–F) model. The maximum capacity of LDHs for fluoride ions and the Gibbs free energy (ΔG0) for the defluoridation process were calculated to be 319.8±5.7 mg/g and −9.0±0.66 kJ/mol, respectively. The negative value of ΔG0 indicates the spontaneous nature of the treatment process. Four kinetic models have been evaluated in order to attempt to fit the experimental data, namely the pseudo-first order, the pseudo-second order, the modified multiplex and the double exponential models. It was found that the modified multiplex model, involving a rapid first order step and a slow second order step most closely described the kinetics. The activation energies for the two steps are 37.2±5.26 and 72.6±4.52 kJ/mol, respectively, suggesting that the rapid step is controlled by diffusion processes, whilst the second step is controlled by the reaction of fluoride with the LDHs.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Water Research - Volume 41, Issue 7, April 2007, Pages 1534–1542
نویسندگان
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