کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767197 | 1424119 | 2017 | 25 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Interpenetrating network of titania and carbon ultrafine fibers as hybrid anode materials for high performance sodium-ion batteries
ترجمه فارسی عنوان
شبکه متقابل الیاف تیتانا و کربن فوق العاده به عنوان ماده یونجه هیبرید برای باتری های سدیم یون با کارایی بالا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Interpenetrating networks (IPNs) of titania, having high cycling stability and rate capability, and carbon, having high electrical conductivity and capacity, ultrafine fibers were fabricated by a co-electrospinning technique in opposite directions. The IPN structure promoted a contact between titania and carbon fibers, minimized strain during ion de-insertion, and prevented agglomeration that shortened the cycling stability. Images from scanning electron microscopy with backscattering electron detector and X-ray diffraction spectra confirm the existence of the IPN structure of both types of fibers. Thermogravimetric analysis and Raman spectroscopy of the composite fibers reveal their 37Â wt% of titania content and 1.2 ratio between disorder and graphitic carbon (ID/IG). A galvanostatic curve displays stable reversible capacities of 202 and 247Â mA h gâ1 for charge and discharge after the fifth cycle at a current density of 25Â mAÂ gâ1. The material had a superior discharge capacity of 151 and 123Â mA h gâ1 at 125 and 250Â mAÂ gâ1, respectively. Moreover, the discharge capacity could be maintained at 134Â mA h gâ1 after 100 cycles at 125Â mAÂ gâ1 with a Coulombic efficiency of more than 98%, presenting a long life cycle of batteries. Therefore, the prepared IPN composite fibers can be an efficient anode for sodium-ion batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 238, 1 June 2017, Pages 349-356
Journal: Electrochimica Acta - Volume 238, 1 June 2017, Pages 349-356
نویسندگان
Ponlawat Udomsanti, Thammasit Vongsetskul, Pimpa Limthongkul, Pramuan Tangboriboonrat, Kittitat Subannajui, Phontip Tammawat,