کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4980996 1453333 2017 58 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Removal of antibiotics from aqueous solutions by green synthesized magnetite nanoparticles with selected agro-waste extracts
ترجمه فارسی عنوان
حذف آنتی بیوتیک ها از محلول های آبی با استفاده از نانوذرات مگنتیت سنتز شده سبز با عصاره های انتخابی زراعی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
چکیده انگلیسی
The present work highlights on efficacy of three types of green synthesized magnetite nanoparticles (Fe3O4 NPs) for the removal of a mixture of seven antibiotics, namely piperacillin (PIP), tazobactam (TAZ), sulfamethoxazole (SUL), tetracycline (TET), trimethoprim (TRI), ampicillin (AMP) and erythromycin (ERY) from aqueous media. Fe3O4 NPs were prepared through an environmentally friendly, facile and economical synthetic route which uses aqueous peel extracts of lemon (Citrus limon), black grapes (Vitis vinifera) and cucumber (Cucumis sativus), and were denoted as Fe3O4(lem), Fe3O4(grp) and Fe3O4(cum), respectively. The magnetic nanoparticles were characterized by XRD, FTIR, SEM, TEM, BET, XPS, and VSM techniques. A Box-Behnken design approach was employed in order to identify the optimum conditions for removal of selected antibiotics. The concentration of antibiotics was determined using high-performance liquid chromatography coupled with diode array detector and mass spectrometer (HPLC-DAD-MS) analysis. The Langmuir, Freundlich and Temkin adsorption isotherm models were used for description of the adsorption equilibrium of studied antibiotics and kinetic studies were conducted. Overall, Fe3O4 NPs synthesized with extracts exhibited high removal (>90%) of studied antibiotics, excepting SUL and TRI, and likewise demonstrated higher efficiency for the purpose of antibiotics removal than Fe3O4 NPs synthesized by a previously reported conventional method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Process Safety and Environmental Protection - Volume 107, April 2017, Pages 357-372
نویسندگان
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