کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4991758 | 1457117 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Renewable syngas production from thermal cracking of glycerol over praseodymium-promoted Ni/Al2O3 catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Renewable syngas production from thermal cracking of glycerol over praseodymium-promoted Ni/Al2O3 catalyst Renewable syngas production from thermal cracking of glycerol over praseodymium-promoted Ni/Al2O3 catalyst](/preview/png/4991758.png)
چکیده انگلیسی
In this study, the kinetics of glycerol pyrolysis over a 3wt%Pr-20wt%Ni/77wt%α-Al2O3 catalyst was investigated. The catalyst was synthesized via wet-impregnation method and was characterized using temperature-programmed calcination (TPC), temperature-programmed reduction (TPR), N2-physisorption, FESEM imaging, X-ray diffraction and CO2-/NH3-temperature-programmed desorption (TPD). The catalytic activity of the as-synthesized 3 wt% Pr-Ni/α-Al2O3 catalyst was evaluated in a stainless steel fixed bed reactor at temperatures that ranged from 973 K to 1073 K and a weight-hourly-space-velocity (WHSV) of 4.5 Ã 104 ml gâ1 hâ1 under the atmospheric condition. The main gaseous products from catalytic glycerol pyrolysis were H2, CO, CO2 and CH4 (descending ranking) with the highest H2 formation rate and H2 yield of 0.02593 mol g catâ1 sâ1 and 29.04%, respectively. The analysis of the kinetic data obtained from the glycerol pyrolysis showed activation energy of 37.36 kJ molâ1. Based on the mechanistic modeling, it can be deduced that the rate determining step of the glycerol pyrolysis was via a single site associative adsorption with molecular surface reaction as the rate-determining step.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Thermal Engineering - Volume 112, 5 February 2017, Pages 871-880
Journal: Applied Thermal Engineering - Volume 112, 5 February 2017, Pages 871-880
نویسندگان
Mohd Nasir Nor Shahirah, Bamidele V. Ayodele, Jolius Gimbun, Su Shiung Lam, Chin Kui Cheng,