کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5135910 1493443 2017 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge
چکیده انگلیسی


- A new GC-detector based on atmospheric pressure chemical ionization is proposed.
- A demonstrator with a total size of 75 × 60 × 25 mm3 is shown.
- Limits of detection in the low ppbv-range are achieved.

In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75 × 60 × 25 mm3 and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1483, 3 February 2017, Pages 120-126
نویسندگان
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