کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5136961 | 1494483 | 2017 | 8 صفحه PDF | دانلود رایگان |
- Simple and reliable ultrasound-assisted digestion procedure was proposed for ASV.
- Simultaneous determination of trace Cd(II) and Pb(II) by an eco-friendly BiFE.
- Applied to the analysis of Cd(II) and Pb(II) in organic unpolished rice samples.
- Information on food safety of Thai organic unpolished rice was presented.
A cost-effective and environmentally friendly method was developed for the simultaneous determination of trace cadmium and lead contaminants in unpolished rice. An ultrasound-assisted digestion (UAD) procedure was ultilized for sample preparation prior to determination of Cd(II) and Pb(II) by anodic stripping voltammetry (ASV) using an eco-friendly bismuth film electrode (BiFE). The efficiency of the proposed UAD procedure was evaluated by certified reference material of glutinous rice powder. The parameters influencing UAD such as solvent system, sample mass, presonication time and sonication time were evaluated. Using the deposition time of 300 s for ASV, linear calibration graphs in a range of 10-200 μg Lâ1 for Cd(II) and 5-200 μg Lâ1 Pb(II) were obtained with detection limits of 0.11 and 0.06 μg Lâ1 for Cd(II) and Pb(II), respectively. Relative standard deviations were 3.5 and 2.3% for 10 μg Lâ1 of Cd(II) and Pb(II), respectively. The developed system was successfully applied to the analysis of Cd(II) and Pb(II) in various types of organic unpolished rice samples and validated by flame atomic absorption spectrometric method. All studied Thai organic unpolished rice samples were not contaminated with Cd(II) and Pb(II).
Journal: Journal of Food Composition and Analysis - Volume 59, June 2017, Pages 145-152