کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5162246 | 1502285 | 2014 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Generation of unusual branched long chain alkanes from hydrous pyrolysis of anammox bacterial biomass
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Generation of unusual branched long chain alkanes from hydrous pyrolysis of anammox bacterial biomass Generation of unusual branched long chain alkanes from hydrous pyrolysis of anammox bacterial biomass](/preview/png/5162246.png)
چکیده انگلیسی
Anammox, the microbial anaerobic oxidation of NH4+ by NO2â to produce N2, is recognised as a key process in the marine, freshwater and soil N cycles, and has been found to be a major sink for fixed inorganic N in the ocean. Ladderane lipids are unique anammox bacterial membrane lipids used as biomarkers for such bacteria in recent and past environmental settings. However, their fate during diagenesis and early catagenesis is not well constrained. In this study, hydrous pyrolysis experiments were performed on anammox bacterial biomass and the generated aliphatic hydrocarbons, present in oil generated at 220-365 °C, were analysed. A unique class of hydrocarbons was detected, and a representative component was isolated and rigorously identified using 2D nuclear magnetic resonance (NMR) spectroscopy. It consisted of C24 to C31 branched long chain alkanes with two internal ethyl and/or propyl substituents. The alkanes were generated above 260 °C, with maximum generation at 320 and 335 °C. Their stable carbon isotopic values were depleted in 13C, similar to carbon isotope values of the original anammox lipids, indicating that they were thermal products generated from lipids of anammox bacterial biomass. A range of sediments from different geological periods where anammox may have been an important process was screened for the presence of these compounds as possible catagenetic products. They were not detected, either because the concentration was too low, or the sediments screened were too immature for them to have been generated, or because the artificially produced products of anammox lipids may not reflect the natural diagenetic and catagenetic products of ladderane lipids.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Geochemistry - Volume 76, November 2014, Pages 136-145
Journal: Organic Geochemistry - Volume 76, November 2014, Pages 136-145
نویسندگان
Darci Rush, Andrea Jaeschke, Jan A.J. Geenevasen, Erik Tegelaar, Jos Pureveen, Michael D. Lewan, Stefan Schouten, Jaap S. Sinninghe Damsté,