A theoretical study of H- and I-abstraction reactions from CH3I molecule by I (2P3/2) atom and IO radical

► H- and I-abstraction reactions from CH3I by I (2P3/2) atom and IO radical. ► Kinetic parameters are calculated using ab initio molecular orbital methods. ► Rate constants are calculated at CCSD(T)/cc-pVnZ//MP2/cc-pVTZ (n = T, Q). ► Rate constants are calculated from 600 to 2500 K and compared to the available literature data.