کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5400052 | 1505913 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Blue photoluminescence and long lasting phosphorescence properties of a novel chloride phosphate phosphor: Sr5(PO4)3Cl:Eu2+
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
A novel blue emitting long lasting phosphorescence phosphor Sr5(PO4)3Cl:Eu2+ is synthesized by solid state method at 1223Â K in reducing atmosphere. The afterglow emission spectrum shows one broad band centered at 441Â nm due to the 5d-4f transition of Eu2+ at six coordinated Sr(II) sites and the color coordinates are calculated to be (0.149, 0.095) which is close to the light blue region. The excitation band is in 240-430Â nm and partly overlaps the solar irradiation on Earth's surface. The long lasting phosphorescence of the optimal sample doping by 0.1Â mol%Eu2+ can be recorded for about 1040Â s (0.32Â mcd/m2). Thermoluminescence shows that there are at least three types of traps corresponding to peaks at 340Â K, 382Â K, 500Â K, respectively. The filling and fading experiments reveal that the traps in Sr5(PO4)3Cl:Eu2+ are independent. The shallow traps (340Â K) essentially contribute to the visible long lasting phosphorescence, while the deep traps (382Â K and 500Â K) are proved to be very stable. Thus, the Sr5(PO4)3Cl:Eu2+ material shows potential applications as not only a long lasting phosphorescence phosphor, but also an optical storage material.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 147, March 2014, Pages 229-234
Journal: Journal of Luminescence - Volume 147, March 2014, Pages 229-234
نویسندگان
Chuanqiang Wu, Jiachi Zhang, Pengfei Feng, Yiming Duan, Zhiya Zhang, Yuhua Wang,