کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5400543 | 1505912 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly selective fluorescent probe for the detection of tin (IV) Ion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
A novel fluorescent compound, 7-diethylamino-3-(2'-(1H-imidazo[4,5-b]phenazine)yl)coumarin (DIPC), was synthesized and employed as a fluorescent probe for detecting tin (IV) ion. Upon addition of tin (IV) ion to the solution of DIPC in DMSO-water (9:1, v/v), DIPC exhibited a considerable red-shift in its absorption spectrum and a decrease in fluorescence intensity. These changes result from tin (IV) ion binding to carbonyl oxygen of coumarin and nitrogen of imidazole, reflecting an enhanced ICT process from N,N-diethylamino unit to imidazole unit. The tin (IV) ion selective response was clearly observed by the naked eye through color change. We also studied the bioimaging application of DIPC for detecting tin (IV) ion in Hela cells. And a significant decrease of the fluorescence from the intracellular area was observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 148, April 2014, Pages 161-164
Journal: Journal of Luminescence - Volume 148, April 2014, Pages 161-164
نویسندگان
Leiming Zhu, Jing Yang, Qiusheng Wang, Lintao Zeng,