کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5404275 | 1392775 | 2006 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The influence of Förster energy transfer on spectral and kinetic characteristics of phosphorescence and thermally activated delayed fluorescence of acriflavine in a polyvinylalcohol matrix
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The influence of Förster energy transfer on spectral and kinetic characteristics of phosphorescence and thermally activated delayed fluorescence of acriflavine in a polyvinylalcohol matrix The influence of Förster energy transfer on spectral and kinetic characteristics of phosphorescence and thermally activated delayed fluorescence of acriflavine in a polyvinylalcohol matrix](/preview/png/5404275.png)
چکیده انگلیسی
Spectral and kinetic characteristics of thermally activated delayed fluorescence (TADF) and phosphorescence of acriflavine in polyvinylalcohol films have been investigated. It was shown that TADF and phosphorescence decay times decrease due to fluorescence resonance energy transfer (FRET) as the concentration of the dye molecules increases. The luminescence spectra of the concentrated solutions are bathochromic shifted with respect to that of the deluted ones. Moreover, TADF and phosphorescence spectra of the concentrated solutions shift to the higher frequency region as emission decays. These effects are determined by the correlation between FRET direction and the heterogeneity of the triplet state lifetimes. Numerical simulations of the spectral and kinetic characteristics of TADF and phosphorescence were made by means of Monte-Carlo integrations, and results were compared with experimental data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 121, Issue 1, November 2006, Pages 75-87
Journal: Journal of Luminescence - Volume 121, Issue 1, November 2006, Pages 75-87
نویسندگان
I.A. Kaputskaya, E.A. Ermilov, S. Tannert, B. Röder, S.K. Gorbatsevich,