کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413815 | 1506635 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Specific salt effects on energy transfer reactions from [Tb(2,6-pyridinedicarboxylate)3]3â to Co(III) complexes in aqueous solutions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Specific cation and anion effects are investigated on reactions of energy transfer from [Tb(dpa)3]3â (dpa = 2,6-pyridinedicarboxylate) to [Co(bpy)3]3+ (bpy = 2,2â²-bipyridine), [Co(en)3]3+ (en=ethylenediamine), [Co(pam)3]3+ (pam = 2-aminomethylpyridine) and [Co(NH3)6]3+ in aqueous solutions. Quenching rate constants of [Tb(dpa)3]3â by [Co(bpy)3]3+ are changed by the added anions in the following order, Clâ > Brâ > ClO4â. However, the order of the quenching rate constants of [Tb(dpa)3]3â by [Co(en)3]3+, [Co(pam)3]3+ and [Co(NH3)6]3+ is different, Clâ â Brâ < ClO4â. The anion effect on the rate constants is discussed in terms of the variation of the distance between energy donor and acceptor in the encounter complexes surrounded by the indifferent ions. Both quenching reactions of [Tb(dpa)3]3â-[Co(bpy)3]3+ and â[Co(en)3]3+ are less affected by coexisting cations. The anion salt effect in the Tb-Co systems is discussed with the comparison of [Ru(bpy)3]2+-[Cr(CN)6]3â system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 128, Issues 1â3, 15 September 2006, Pages 71-76
Journal: Journal of Molecular Liquids - Volume 128, Issues 1â3, 15 September 2006, Pages 71-76
نویسندگان
Munetaka Iwamura, Makoto Morita, Takuhiro Otsuka, Youkoh Kaizu,