کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5420823 | 1395473 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solid-state NMR and EPR analysis of carbon-doped titanium dioxide photocatalysts (TiO2âxCx)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Solid-state NMR and EPR analysis of carbon-doped titanium dioxide photocatalysts (TiO2âxCx) Solid-state NMR and EPR analysis of carbon-doped titanium dioxide photocatalysts (TiO2âxCx)](/preview/png/5420823.png)
چکیده انگلیسی
Carbon-doped TiO2 have received attention recently because of their potential for environmental photocatalysis and solar hydrogen conversion applications. Three different carbon-doped TiO2 nanoparticle materials were synthesized via sol-gel and hydrothermal procedures, and analyzed by 13C solid-state nuclear magnetic resonance (SSNMR) and other methods to characterize the environment of the doping species. UV/vis spectra and powder X-ray diffraction (XRD) patterns showed that the synthesized materials absorbed visible light and their crystal structures corresponded to anatase. 13C SSNMR analyses of TiO2âxCx displayed signals corresponding to carbonate-type or sp2-type carbon species. Variable contact CP-MAS and dipolar dephasing analyses gave evidence for the presence and proximity of H atoms near these carbonate species. Electron paramagnetic resonance (EPR) spectroscopy showed that the thermally oxidized TiO2âxCx displayed a complex mixture of point defects, electron and hole trapping centers, all attributable to the incorporation of carbon, while the XPS data ruled out the presence of carbide species.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volume 35, Issue 2, April 2009, Pages 74-81
Journal: Solid State Nuclear Magnetic Resonance - Volume 35, Issue 2, April 2009, Pages 74-81
نویسندگان
Enrique A. Reyes-Garcia, Yanping Sun, Karla R. Reyes-Gil, Daniel Raftery,