کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5420976 | 1507517 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Quadrupolar relaxation of hyperpolarized krypton-83 as a probe for surfaces
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work reports the first systematic study of relaxation experienced by the hyperpolarized (hp) noble gas isotope 83Kr (I=9/2) in contact with surfaces. The spin-lattice relaxation of 83Kr is found to depend strongly on the chemical composition of the surfaces in the vicinity of the gas. This effect is caused by quadrupolar interactions during brief periods of surface adsorption that are the dominating source of longitudinal spin relaxation in the 83Kr atoms. Simple model systems of closest packed glass beads with uniform but variable bead sizes are used for the relaxation measurements. The observed relaxation rates depend strongly on the chemical treatment of the glass surfaces and on the surface to volume ratio. Hp 83Kr NMR relaxation measurements of porous polymers with pore sizes of 70-250 μm demonstrate the potential use of this new technique for material sciences applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volume 29, Issues 1â3, February 2006, Pages 79-84
Journal: Solid State Nuclear Magnetic Resonance - Volume 29, Issues 1â3, February 2006, Pages 79-84
نویسندگان
Karl F. Stupic, Zackary I. Cleveland, Galina E. Pavlovskaya, Thomas Meersmann,