کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5436025 1509546 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
First-principles modeling of anisotropic anodic dissolution of metals and alloys in corrosive environments
ترجمه فارسی عنوان
مدل سازی اولیهای از انحلال آنیدوپروپیک آنودیک فلزات و آلیاژها در محیطهای خورنده
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی

There have been extensive experimental observations of the anisotropic corrosion behavior of metals and alloys, and their mechanisms were assumed to be correlated with the so-called surface energy or the work function. However, to date, a specified mechanism or theory to interpret anisotropic corrosion behavior remains unclear. Here, we determine the anisotropic anodic dissolution of metals and alloys in corrosive environments by developing a formula to specify the relationship between the electrode potential (U) and the current density (I) by considering the basic parameters of our defined surface energy density (Esurf/ρ) and the work function (Φ). Therefore, we build an ab initio model to evaluate the anisotropic anodic dissolution behavior of metals and alloys using the inputs obtained within density functional theory. This theory is further validated in the case of variations in the crystallographic planes of Mg. Moreover, some selected alloying additions such as Ga, Cd, Hg, In, As, and Cr are theoretically elucidated to effectively reduce the anodic dissolution rates of the Mg matrix to some extent, in close agreement with available experimental observations. This model is capable of predicting the anisotropic anodic dissolution behavior, providing a promising perspective for designing better corrosion-resistant alloys.

334

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Materialia - Volume 130, 15 May 2017, Pages 137-146
نویسندگان
, , , , , ,