کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5458779 | 1516167 | 2017 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Co3O4 nanoparticle-decorated hierarchical flower-like α-Fe2O3 microspheres: Synthesis and ethanol sensing properties
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
Co3O4 nanoparticle-decorated hierarchical flower-like α-Fe2O3 microspheres were prepared via a facile two-step method and subsequent annealing. The structure, morphology and surface characteristics of the as-prepared products were analyzed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscope (TEM) and Brunauer-Emmett-Teller (BET). Considering the potential applications, the gas sensing performances of the sensor based on α-Fe2O3/Co3O4 composites and pure α-Fe2O3 microspheres were investigated towards a series of volatile organic compounds. The response of hierarchical α-Fe2O3/Co3O4 composites sensor to 100 ppm ethanol at operating temperature of 170 °C is about 16.1, which is twice as much as the pure α-Fe2O3 microspheres sensor at 300 °C. Moreover, a dramatic reduction of response/recovery time (3.3 s/5.4 s) has been achieved at different operating temperature. The enhanced sensitivity performance is mainly due to its unique hierarchical structure, which provides high surface area, a large number of active sites, and the synergistic effect between n-type α-Fe2O3 and p-type Co3O4.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 727, 15 December 2017, Pages 52-62
Journal: Journal of Alloys and Compounds - Volume 727, 15 December 2017, Pages 52-62
نویسندگان
Bingxia Yang, Jingyuan Liu, Hao Qin, Qi Liu, Xiaoyan Jing, Hongquan Zhang, Rumin Li, Guoqing Huang, Jun Wang,