کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5746236 | 1618787 | 2017 | 12 صفحه PDF | دانلود رایگان |
- A reduced intensity of high-MW peaks in the filtration effluent was observed.
- Fulvic- and humic acid were partly rejected by the cake layer.
- Dominant low-MW SMPs identified include aromatics, alcohols, alkanes and esters.
- The SMP numbers, types and compositions were different down the treatment train.
- SMPs exhibited both biodegradable and recalcitrant characteristics.
The formation, composition and characteristics of soluble microbial products (SMPs) were investigated in a novel system which coupled a sequencing batch reactor with a cake filtration system. Both suspended solids (SS) and turbidity were significantly removed, resulting in effluent SS of 0.12 mg Lâ1 and turbidity of 0.72 NTU after cake filtration. The average concentrations of proteins and carbohydrates decreased respectively from 4.0 ± 0.4 and 7.1 ± 0.6 mg/L in the sequencing batch reactor (SBR) mixed liquor, to 0.85 ± 0.21 and 1.39 ± 0.29 mg/L in the cake filtration effluent. Analysis of the molecular weight (MW) distribution of SMPs revealed a substantial reduction in the intensity of high-MW peaks (503 and 22.71 kDa) after cake filtration, which implied the sludge cake layer and the underlying gel layer may play a role in the effectiveness of cake filtration beyond the physical phenomenon. Three-dimensional excitation emission matrix fluorescence spectroscopy indicated that polycarboxylate- and polyaromatic humic acids were the dominant compounds and a noticeable decrease in the fraction of these compounds was observed in the cake filtration effluent. Analysis with GC-MS set for detecting low-MW SMPs identified aromatics, alcohols, alkanes and esters as the dominant compounds. SMPs exhibited both biodegradable and recalcitrant characteristics. More SMPs (total number of 91) were accumulated during the SBR start-up stage. A noticeable increase in the aromatic fractions was seen in the SBR effluent accoutring for 39% of total compounds, compared to the SBR mixed liquor (28%). Fewer compounds (total number of 66) were identified in cake filtration effluent compared to the SBR effluent (total number of 75).
Journal: Chemosphere - Volume 184, October 2017, Pages 1286-1297