کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
576499 | 1453078 | 2015 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ozonation of benzotriazole and methylindole: Kinetic modeling, identification of intermediates and reaction mechanisms
ترجمه فارسی عنوان
استحصال بنزوتریازول و متیلندول: مدل سازی جنبشی، شناسایی واسطه ها و مکانیزم های واکنش
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کلمات کلیدی
آلاینده های در حال ظهور، ازن، نرخ ثابت، شناسایی واسطه ها، مکانیسم واکنش
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
چکیده انگلیسی
The ozonation of 1H-benzotriazole (BZ) and 3-methylindole (ML), two emerging contaminants that are frequently present in aquatic environments, was investigated. The experiments were performed with the contaminants (1 μM) dissolved in ultrapure water. The kinetic study led to the determination of the apparent rate constants for the ozonation reactions. In the case of 1H-benzotriazole, these rate constants varied from 20.1 ± 0.4 Mâ1 sâ1 at pH = 3 to 2143 ± 23 Mâ1 sâ1 at pH = 10. Due to its acidic nature (pKa = 8.2), the degree of dissociation of this pollutant was determined at every pH of work, and the specific rate constants of the un-dissociated and dissociated species were evaluated, being the values of these rate constants 20.1 ± 2.0 and 2.0 ± 0.3 Ã 103 Mâ1 sâ1, respectively. On the contrary, 3-methylindole does not present acidic nature, and therefore, it can be proposed an average value for its rate constant of 4.90 ± 0.7 Ã 105 Mâ1 sâ1 in the whole pH range 3-10. Further experiments were performed to identify the main degradation byproducts (10 mg Lâ1 of contaminants, 0.023 g hâ1 of ozone). Up to 8 intermediates formed in the ozonation of 3-methylindole were identified by LC-TOFMS, while 6 intermediates were identified in the ozonation of 1H-benzotriazole. By considering these intermediate compounds, the reaction mechanisms were proposed and discussed. Finally, evaluated rate constants allowed to predict and modeling the oxidation of these micropollutants in general aquatic systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 282, 23 January 2015, Pages 224-232
Journal: Journal of Hazardous Materials - Volume 282, 23 January 2015, Pages 224-232
نویسندگان
F. Javier Benitez, Juan L. Acero, Francisco J. Real, Gloria Roldán, Elena RodrÃguez,