کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
592956 1453924 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of the graphene content and the treatment temperature on the supercapacitive properties of VOx/graphene nanocomposites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Effects of the graphene content and the treatment temperature on the supercapacitive properties of VOx/graphene nanocomposites
چکیده انگلیسی


• VOx/graphene hybrid materials were fabricated using a simple hydrothermal method.
• The performance of VOx–n% GO-T is affected by GNS content and annealing temperature.
• The VOx–7.4% GO-300 composite electrode shows superior capacitive properties.
• The excellent performance is attributed to the improved dispersion and utilization.

The vanadium oxides (VOx)/graphene hybrid materials constructed from 2D graphene nanosheets (GNS) and VOx are successfully prepared by a simple two-step procedure including solvothermal method and subsequent thermal treatment. Effects of the GNS content and the annealing temperature on the microstructure and morphology of as-obtained composites are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. Importantly, the electrochemical properties of as-prepared composites are systematically investigated by cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy, which are highly dependent on the content of GNS in composite and the annealing temperature. Furthermore, the VOx–7.4% GO-300 composite electrode exhibits the largest specific capacitance and the most excellent rate capability among these composites. These encouraging results illustrate the exciting potential for high performance energy storage devices based on the VOx–7.4% GO-300 composite.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 449, 1 May 2014, Pages 148–156
نویسندگان
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