کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6469833 1424103 2017 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Graphene-wrapped Li4Ti5O12 hollow spheres consisting of nanosheets as novel anode material for lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Graphene-wrapped Li4Ti5O12 hollow spheres consisting of nanosheets as novel anode material for lithium-ion batteries
چکیده انگلیسی


- Li4Ti5O12@graphene exhibits higher capacities and superior electrochemical performances..
- Graphene-wrapping reduces work function of composite and enhances Li+ diffusion kinetics.
- The heterojunction interface plays a positive impact on the improved performance.

Flower-like Li4Ti5O12 hollow microspheres consisting of nanosheets are prepared via a hydrothermal process, and subsequently wrapped by graphene through electrostatic interactions. In comparison with pristine Li4Ti5O12, Li4Ti5O12@graphene exhibited higher capacities and improved rate capability in the 0.01-3.0 V or 1.0-3.0 V potential range. Li4Ti5O12@graphene composite shows specific capacity of 272.7 mAh g−1 at 750 mA g−1 after 200 cycles in the potential range from 0.01 to 3.0 V, while the pristine Li4Ti5O12 only delivered a discharge capacity of 235.6 mAh g−1. The improved electrochemical performances of Li4Ti5O12@graphene should be attributed to lower charge-transfer resistances, larger lithium-ion diffusion coefficient and lower activation energy. The electrons transfer at Li4Ti5O12/graphene heterojunction interface, originating from difference in the work function of two composites, reduces the localized work function of the composites, decreases energy required for electrons to escape and consequently results in the improved electrochemical performances.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 254, 10 November 2017, Pages 287-298
نویسندگان
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