کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6471354 1424127 2017 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
ترجمه فارسی عنوان
سنتز الکتروشیمیایی پلی هیدرازونهای مبتنی بر تریدنیولامین
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

Triphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn't be formed. The results of electrochemical, spectroelectrochemical investigation of small molecules, as well as their polymers obtained by electropolymerization, are presented. The comparative study of electropolymerization and doping process by IR, EPR, potentiostatic and potentiodynamic UV-Vis-NIR, DEIS spectroelectrochemical techniques was performed to determine the reaction path, charge carriers and conductivity of polymeric layers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 230, 10 March 2017, Pages 10-21
نویسندگان
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