کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6473091 | 1424142 | 2016 | 7 صفحه PDF | دانلود رایگان |
Cross-linked carbon nanofiber (CLCNF) was successfully prepared by directly carbonizing electrospun polyacrylonitrile (PAN) nanofiber. Comparing to non-cross-linked carbon nanofiber (NCLCNF) obtained via carbonizing of pre-oxidation PAN nanofiber, CLCNF shows better conductivity owing to its cross-linked structure. Then CLCNF was used as scaffold to support polyaniline (PANi) nanorods for supercapacitor electrode material. The hierarchical CLCNF/PANi composite displays a capacity of 206CÂ gâ1 at 0.5Â AÂ gâ1 with excellent rate capability (remains 49% even at 800Â AÂ gâ1), which is much higher than that of NCLCNF/PANi composite (17%). More interestingly, supercapacitor device based on CLCNF/PANi composite achieves 75.3% capacity retention after 10000 charge-discharge cycles at 10Â AÂ gâ1, suggesting excellent cycle stability. All these experimental results indicate that this method for fabricating CLCNF is a substantial advancement towards the practical applications of carbon nanofiber in energy conversion and storage field.
Journal: Electrochimica Acta - Volume 215, 10 October 2016, Pages 29-35