Mediated electron transfer with monooxygenases-Insight in interactions between reduced mediators and the co-substrate oxygen

- Electroenzymatic conversion of p-xylene to 2,5-dimethylphenol is possible.
- Electrode material has a strong impact on the overall performance of mediated electron transfer.
- Interaction of cobalt(III)sepulchrate with oxygen is quantified.
- [Cp*Rh(I)(bpy)H]+ is less oxygen-dependent but show also interactions with oxygen.