کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6594726 1423729 2018 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A sustainable process design to produce diethyl oxalate considering NOx elimination
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A sustainable process design to produce diethyl oxalate considering NOx elimination
چکیده انگلیسی
Diethyl oxalate (DEO) is widely used in fine chemical industry. In comparison with traditional esterification process, carbon monoxide coupling process is a novel routine for DEO production. This environmentally friendly process provides better selectivity and yield. Its unique feature is that a closed regeneration-coupling circulation is formed. Toxic byproduct-nitric oxide (NO) from coupling reaction is recycled to re-produce ethyl nitrite through regeneration reaction. This avoids significant amount of NOx emission. However, due to a few NOx emission, a contaminant handling system is applied for environmental protection. A systematical environmental analysis is also carried out to assess this process. Regeneration-coupling circulation brings interaction behaviors and some trade-offs including reactor size and recycle flowrate, regeneration and coupling reaction, loss of reactants and NO emission. Thus, a rigorous steady simulation is established to investigate these trade-offs. Then DEO process is optimized to obtain the optimal design. Finally a more economic flowsheet to produce DEO is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Computers & Chemical Engineering - Volume 115, 12 July 2018, Pages 198-212
نویسندگان
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