کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6601831 | 1424072 | 2018 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sulfur-infiltrated yeast-derived nitrogen-rich porous carbon microspheres @ reduced graphene cathode for high-performance lithium-sulfur batteries
ترجمه فارسی عنوان
کربن متخلخل کربن متخلخل حاوی نیتروژن حاوی مخمر سولفات @ کاهش کاتد گرافین برای باتری های لیتیوم-سولفور با کارایی بالا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The defects of polysulfide dissolution and sulfur insulating causes in Li-sulfur batteries have effectively diminished by immobilizing sulfur in porous carbon microspheres via the interactions of doping-nitrogen and encapsulating-reduced graphene. The nitrogen-rich porous carbon microspheres were prepared by using yeast as natural precursor and high content of nitrogen (up to 8.52%) doped carbon microspheres was confirmed by the elemental analysis. As cathode for lithium-sulfur batteries, the rGO@HYC/S composite exhibits a high retention capacity of 921â¯mAâ¯hâ¯gâ1 at 0.2â¯C and 675â¯mAâ¯hâ¯gâ1 at 1â¯C over 200 cycles. The battery delivers low capacity decay rate of 0.09% and stable coulombic efficiency about 98% at 1â¯C during the 200 cycles. Further, we reveal that the enhanced electrochemical performance is ascribed to a hollow porous structure of carbon framework for sulfur storage, carbon matrix exerted by nitrogen-doping for polysulfide adsorption, rGO wrapper for polysulfide interception and conductivity improvement.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 285, 20 September 2018, Pages 317-325
Journal: Electrochimica Acta - Volume 285, 20 September 2018, Pages 317-325
نویسندگان
Yujiao Li, Yurong Cai, Zhouyang Cai, Jianghui Xu, Jegatheeswaran Sonamuthu, Guocheng Zhu, Jiri Militky, Wanhui Jin, Juming Yao,