کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6603333 1424086 2018 25 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrodeposition of high-purity nanostructured iron films from Fe(II) and Fe(III) non-aqueous solutions based on ethylene glycol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrodeposition of high-purity nanostructured iron films from Fe(II) and Fe(III) non-aqueous solutions based on ethylene glycol
چکیده انگلیسی
Ethylene glycol was studied as solvent for the electrodeposition of iron from both bivalent and trivalent iron chloride solutions. Using cyclic voltammetry (CV) on Pt electrodes, the impossibility to directly reduce Fe(III) ions to metallic state Fe(0) was evidenced with the formation of Fe(II) species as intermediate step for iron plating. Linear sweep voltammetries (LSVs) were carried out on copper substrate confirming the results previously obtained on platinum. Potentiostatic depositions were performed from both Fe(II) and Fe(III) solutions in a broad potential interval (from −1.5 to −2.3 V vs Pt) to define the threshold value for iron reduction and film formation: the best results were obtained at −1.7 V vs Pt for Fe(II) solution and at −2.3 V vs Pt for Fe(III) one. Deposits were characterized with field emission scanning electron microscope (FE-SEM) showing a nanostructured morphology with no traces of oxygen in the deposits, resulting in a pure metallic plated iron: films showed a corrosion potential (Ecorr = −0.54 V vs Ag/AgCl ) in 3.5 wt% NaCl aqueous solution similar to high purity metallurgical iron sheet (Ecorr = −0.4 V vs Ag/AgCl ). X-Ray diffraction patterns showed a preferential orientation of the nanocrystalline deposit along the BCC [110] direction. Vibrating sample magnetometer (VSM) analysis showed a good saturation magnetization (1500 ± 100 kA/m) and low coercivity (∼20 Oe) indicative of a high purity iron film.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 271, 1 May 2018, Pages 576-581
نویسندگان
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