کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6604208 | 1424092 | 2018 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High efficiency oxygen evolution reaction enabled by 3D network composed of nitrogen-doped graphitic carbon-coated metal/metal oxide heterojunctions
ترجمه فارسی عنوان
واکنش تکامل اکسیژن در واکنش های اکسیژن فعال توسط شبکه سهبعدی متشکل از هتروژونهای اکسید فلزی / فلز فلزی با پوشش نیتروژنی
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کلمات کلیدی
واکنش تکامل اکسیژن، آنالوگهای آبی پروس، کربن نیتروژنه ساختار سازمانی، فلز غیر گرانبها،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The ability to develop low-cost highly efficient electrocatalyst for oxygen evolution reaction (OER) is key to the overall water splitting device that represents a viable and promising source of alternative energy. Herein, we crafted three-dimensional (3D) network comprising nitrogen-doped graphitic carbon-coated heterojunctions (denoted NC-Ni0.36Fe0.64/MnOx) via one-step calcination of hybrid precursors containing ternary Prussian blue analogues and polymers. The NC-Ni0.36Fe0.64/MnOx nanocomposites were then exploited as catalysts for OER, displaying exceptional performance with a small overpotential of 300â¯mV to reach 10â¯mAâ¯cmâ2, a low Tafel slope of 43 mV/dec and an outstanding stability without deactivation over a 10-h OER. Notably, compared to commercial RuO2 catalysts, NCNi0.36Fe0.64/MnOx catalysts demonstrated much lower overpotential and Tafel slope. The excellent OER performance can be attributed to the presence of high-valence oxidized metal species (Ni2+, Fe2+ and Mn2+) at the heterostructured interface as well as pyridinic N-doped carbon species on highly conductive graphitic carbon network, thus greatly facilitating the electron-withdrawing from OHâ and thus charge transfer during OER. This simple yet effective strategy may open new possibilities for creating a wide range of low-cost, high-efficiency, non-precious transition metal OER catalysts for the overall water splitting.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 265, 1 March 2018, Pages 620-628
Journal: Electrochimica Acta - Volume 265, 1 March 2018, Pages 620-628
نویسندگان
Qi Hu, Xiufang Liu, Chaoyun Tang, Liangdong Fan, Xiaoyan Chai, Qianling Zhang, Jianhong Liu, Chuanxin He,